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General
- Tin is a chemical
element with the symbol Sn and atomic number 50.
- This silvery,
malleable poor metal that is not easily oxidized in air and resists
corrosion, is found in many alloys and is used to coat other metals to
prevent corrosion.
- Tin is obtained
chiefly from the mineral cassiterite, where it occurs as an oxide. It
can be alloyed with copper to make bronze. Pewter alloys contain from
85% up to 99% tin.
Process
- Tin is produced by
reducing the ore with coal in a reverberatory furnace. This metal is a
relatively scarce element with an abundance in the Earth's crust of
about 2 ppm, compared with 94 ppm for zinc, 63 ppm for copper, and 12
ppm for lead.
- Most of the world's
tin is produced from placer deposits. The only mineral of commercial
importance as a source of tin is cassiterite , although small quantities
of tin are recovered from complex sulfides such as stannite, cylindrite,
franckeite, canfieldite, and teallite.
- Secondary, or scrap,
tin is also an important source of the metal.
- Tin acts as a
catalyst when oxygen is in solution and helps accelerate chemical
attack. Tin forms the dioxide SnO2 when it is heated in the presence of
air. SnO2, in turn, is feebly acidic and forms stannate salts with
basic oxides.
Application
- The most important
salt formed is stannous chloride, which has found use as a reducing
agent and as a mordant in the calico printing process.
- Electrically
conductive coatings are produced when tin salts are sprayed onto glass.
These coatings have been used in panel lighting and in the production of
frost-free windshields.
- Tin is also used in
solders for joining pipes or electric circuits, in bearing alloys, in
glass-making, and in a wide range of tin chemical applications.
- Tin is added to some
dental care products as stannous fluoride .
Report
- Most secondary tin
has been produced in the United States from various scrapped alloys of
tin and recycled in those same alloy industries.
- The tin was imported
from many countries and was held in U.S. warehouses by trading fi rms
until sold to customers. Foreign-owned trading fi rms tended to dominate
the marketing of imports.
- United States imports
of refined tin came mostly from Peru, Bolivia, Indonesia, China, and
Brazil, in descending order.
- Reports indicated
that China, the world’s leading tin producer from mine and smelter
sources, was experiencing a steady rise in tin imports in 2005 as the
supply of domestic tin concentrate remained tight.
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