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General

• Thionyl chloride or thionyl dichloride is an inorganic compound with the formula SOCl2.
• Thionyl chloride is a reactive chemical reagent used in chlorination reactions.
• It is a colorless, distillable liquid at room temperature and pressure that decomposes above 140 °C.

Process

• N-Acylhydrazones of o-hydroxyaryl ketones react with thionyl chloride to give N-arylhydrazonoyl chlorides in good yields.
• If the thionyl chloride was irreversibly adsorbed or reacted, the pressure would be expected to decrease and remain at that lower pressure upon expansion. This discovery lead to a search for a new getter for Li/SOClz batteries.

Uses

• Thionyl chloride is used inside lithium-thionyl chloride batteries as the positive active material with lithium as the negative active material.
• It is also used as a reagent for the production of other chemical compounds or materials.
• It is also used during synthesis of drugs, vitamins, and herbicides. It is commercially available and used in industrial chemical reactions.

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