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Methyl Isobutyl Ketone
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General
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Methyl
isobutyl ketone (MIBK) is a colorless liquid with an odor similar to
mothballs.
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MIBK is
also known as 4-methyl-2-pentanone, hexone and isopropylacetone.
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MIBK
occurs naturally in oranges, grapes and vinegar.
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MIBK is
usually in liquid form, MIBK can change into a gas. MIBK will dissolve in
water, alcohols, benzenes and ethers.
Process
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Acetone is first converted to
diacetone alcohol (DAA) by aldol condensation of acetone over basic or
acid catalysts, DAA is dehydrated to mesityl oxide (MO) and MO is
selective hydrogenated to MIBK over nickel, copper or noble metal
catalysts
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Direct conversion of acetone into
MIBK can be performed by liquid phase processes, using palladium on a
great variety of supports, with conversions between 30 and 40% and high
selectivities
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Gas-phase processes operating at
atmospheric pressure are potentially much more simple and cheap. However,
lower selectivities to MIBK than those observed for liquid phase processes
have been observed (60-80%), along with a more pronounced deactivation of
the catalyst, especially when acid supports are used.
Application
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MIBK
is used as a solvent in factories that produce paints, rubber products,
chemicals and machinery. As a solvent, it is used in pesticide
application. Pharmaceutical companies that produce prescription drugs
also use MIBK.
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MIBK
is also used in insecticides that control garden insects, greases and
oil used as lubricants, automotive chemicals, pet flea and tick
products, shoe polish, wood office furniture, and clear finishes,
undercoats and primers.
- Methyl isobutyl
ketone (MIBK) can be used to extract gold, silver and other precious
metals from cyanide solutions, such as those found on gold mines, to
determine the levels of those dissolved metals. Another solution used
for this purpose is Di Iso Butyl Ketone (DIBK).
Market
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Demand for MiBK globally
is estimated to exceed 300 000 tons per year.
- Global demand for
MIBK was 287 000 tonne. Asia-Pacific is the largest consumer with demand
of 78 500 tonne/year, followed by the US with 62 000 tonne/year, then
western Europe with 56 000 tonne/year.
Report
- MIBK is a Food and
Drug Administration (FDA)-approved indirect food additive for adhesives,
paper and paperboard, and polymers.
- The CS spray used
by police forces in the UK consists of a 5% (w/v) solution of CS in MIBK,
comprising 1.5 grams (g) of CS dissolved in a total volume of 30
millilitres (ml), contained in a canister with nitrogen as a propellant.
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