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- Hafnium is a
chemical element that has the symbol Hf and atomic number 72. A
lustrous, silvery gray tetravalent transition metal, hafnium resembles
zirconium chemically and it is found in zirconium minerals.
- Hafnium is used in
tungsten alloys in filaments and electrodes, in integrated circuits as a
gate insulator for transistors, and as a neutron absorber in control
rods in nuclear power plants.
- Hafnium is
estimated to make up about 0.00058% of the Earth's upper crust by
weight. It is found combined in natural zirconium compounds but it does
not exist as a free element in nature.
- Minerals that
contain zirconium, such as alvite [(Hf, Th, Zr)SiO4 H2O], thortveitite,
and zircon (ZrSiO4), usually contain between 1 and 5% hafnium.
- Hafnium and
zirconium have nearly identical chemistry, which makes the two difficult
to separate.
- About half of all
hafnium metal manufactured is produced as a by-product of zirconium
refinement. This is done through reducing hafnium chloride with
magnesium or sodium in the Kroll process.
- Hafnium is found
in various alloyed and unalloyed forms such as plate, strip, sheet, rod,
wire and tube – similar to zirconium metal.
- Hafnium is used to
make control rods for nuclear reactors because of its ability to absorb
neutrons , excellent mechanical properties and exceptional
corrosion-resistance properties.
- Hafnium is used in
gas-filled and incandescent lamps, for scavenging oxygen and nitrogen.
- A hafnium-based
compound is employed in gate insulators in the 45 nm generation of
integrated circuits from Intel, IBM and others.
- Hafnium
oxide-based compounds are practical high-k dielectrics, allowing
reduction of the gate leakage current which improves performance at such
scales.
- DARPA has been
intermittently funding programs in the US to determine the possibility
of using a nuclear isomer of hafnium to construct small, high yield
weapons with simple x-ray triggering mechanisms—an application of
induced gamma emission.
- Small additions of
hafnium increase the adherence of protective oxide scales on nickel
based alloys.
- Hafnium improves
thereby the corrosion resistance especially under cyclic temperature
conditions that tend to break oxide scales by inducing thermal stresses
between the bulk material and the oxide layer.
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