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Dimethyl Amino Ethyl
Acrylate
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2-Dimethylaminoethyl acrylate (ADAME) is a yellowish liquid with a
pungent odor.
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World-wide and in Japan, 95-97% of this substance is used to produce
DMAEA quarternary ammonium salts which are used to produce polymers for
industries such as water-treatment and paper-making.
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2-(DiMethylAmino) Ethyl Acrylate (DMAEA) used in migration of monomer
studies because of its small molecular weight and its distinctive
Raman peaks when compared to Bis-A Epoxy Acrylate.
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A
series of acrylamide/dimethylaminoethylacrylate methyl chloride
copolymers (AM-co-DMAEA) was evaluated as flocculants for model
Precipitated Calcium Carbonate (PCC) in distilled water.
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Copolymers of acrylamide and quaternised dimethylaminoethyl acrylate (DMAEA-Q)
constitute an economically important range of cationic poly-
electrolytes used in sludge conditioning.
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Cationic polyphosphazenes were synthesized by a substitution reaction of
poly(dichloro)phosphazene with 2-dimethylaminoethanol (DMAE) or
2-dimethylaminoethylamine (DMAEA)
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The
grafting of a mixture of DMAEA and MMA or that of DMAPAA and MMA was
carried out to obtain high grafting %.
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DMAEA
and OEG-A monomer conversions were determined via 1H NMR spectroscopy,
comparing the signal area from the vinyl protons (d ~ 5.4-6.3 ppm, 3H/5
mol) to the signal area from the methylene oxide (d ~ 3.6 ppm, 30 H/mol)
and methyl adjacent to amine (d ~ 2.8 ppm, 6H/mol) groups, respectively
for OEG-A and DMAEA.
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A new
transesterification method for preparing N, N-dimethylaminoethyl
acrylate (DMAEA) from methyl acrylate (MA) and dimethylaminoethanol (DMAE)
was carried out in the presence of organotin catalyst.
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The
synthesis of DMAEA/styrene amphiphilic diblock copolymers, using
Automatic Continuous Online Monitoring of Polymerization reactions
(ACOMP). Poly(DMAEA) is a pH sensitive polymer with wide applications in
pharmaceutical and water treatment industries yet challenging due to
possible interaction of its amino group with catalysts.
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ADAM
and MADAM are quaternized with either methyl chloride or dimethyl
sulfate in a closed system to produce ADAMMC, ADAMDMS, MADAMMC and
MADAMDMS.
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If
released into water, dimethylaminoethyl acrylate is expected to degrade
to acrylate and 2-dimethylaminoethanol by hydrolysis.
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Arkema,
which is the world number three in acrylics is to build a new production
line for dimethyl amino ethyl acrylate (DMAEA) at Carling-Saint. Carling
is one of the largest acrylic acid plants in the world.
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